Синтез металлоорганического каркаса (ZIF-8) и применение для очистки сточных вод: обзор
Просмотры: 1 / Загрузок PDF: 0
DOI:
https://doi.org/10.32523/3107-278X-2026-154-1-37-59Ключевые слова:
металлоорганические каркасы (MOF), ZIF-8, удаление тяжелых металлов, очистка воды, загрязнениеАннотация
Аннотация. В связи с интенсивным ростом промышленности и сельского хозяйства из года в год усиливается загрязнение окружающей среды ионами тяжелых металлов. Тяжелые металлы чрезвычайно опасны для человека и оказывают пагубное воздействие на окружающую среду и экосистемы. Удаление ионов тяжелых металлов из сточных вод является неотложной задачей, требующей значительного внимания как с экологической, так и с коммерческой точки зрения. Для решения таких проблем, как повышение экономической эффективности, масштабируемость, удаление нескольких металлов, возможность повторного использования и т. д., разрабатываются передовые материалы, которые призваны заменить традиционные методы очистки воды или внедрить современные технологии. Для решения этих проблем особое значение имеют металлоорганические каркасы (MOF), являющиеся новым типом трехмерных органическо-неорганических гибридов, особенно в области адсорбции. В данной статье представлены различные методы синтеза цеолитового каркаса имидазола-8 (ZIF-8), состоящего из одного вида материала MOF - из атомов металлического цинка и 2-метилимидазола, а также их характеристики. Также считается, что (ZIF-8) является хорошо известным материалом для очистки сточных вод, обладающим высокой адсорбционной способностью и уникальными свойствами для фотокаталитических материалов. Кроме того, были обсуждены последние достижения в области использования, синтеза и другие применения MOF для эффективного удаления тяжелых металлов из воды.
Скачивания
Библиографические ссылки
Fayemiwo, O., Daramola, M., & Moothi, K. (2018). Tannin-based adsorbents from green tea for removal of monoaromatic hydrocarbons in water: preliminary investigations. Chem. Eng. Commun. J, 174, 310-317. https://doi.org/ 10.1080/00986445.2017.1409738
Dutta, R., Mohammad, S. S., Chakrabarti, S., Chaudhuri, B., Bhattacharjee S., & Dutta, B. K. (2010). Unveiling the adsorption mechanism of zeolitic imidazolate framework-8 with high removal efficiency on copper ions from aqueous solutions. Dalton Trans, 82, 138-146. https://doi.org/ 10.1039/C6DT01827K
Shannon, M. A., Bohn, P. W., Elimelech, M., Georgiadis, J. G., Marinas, B. J., & Mayes, A. M. (2008). Science and technology for water purification in the coming decades. Nature, 452, 301-310. https://doi.org/10.1038/nature06599
Vorosmarty, C. J., Green, P., Salisbury, J., & Lammers, R. B. (2000). Global water resources: vulnerability from climate change and population growth. Science, 289, 284-288. https://doi.org/10.1126/science.289.5477.284
Vorosmarty, C. J., McIntyre, P. B., Gessner, M. O., Dudgeon, D., Prusevich, A., Green, P., Glidden, S., Bunn, S. E., Sullivan, C. A., Liermann, C. R., & Davies, P. M. (2010). Global threats to human water security and river biodiversity. Nature, 467, 555-561. https://doi.org/10.1038/nature09549
Lapworth, D. J., Baran, N., Stuart, M. E., & Ward, R. S. (2012). Emerging organic contaminants in groundwater: a review of sources, fate and occurrence environ. Pollut, 163, 287-303. https://doi.org/10.1016/j.envpol.2011.12.034
Liang, W., Wang, B., Cheng, J., Xiao, D., Xie, Z., & Zhao, J. (2021). Preparation of Co/Cr-MOFs for efficient removal of fleroxacin and rhodamine B. J. Hazard. Mater, 401, 123718. https://doi.org/10.1515/gps-2024-0195
Joseph, L., Jun, B. M., Jang, M., Park, C. M., Munoz-Senmache, J. C., Hernandez Maldonado, A. J., Heyden, A., Yu, M., & Yoon, Y. (2019). Removal of contaminants of emerging concern by metal-organic framework nanoadsorbents: a review. Chem. Eng. J, 369, 928-946. https://doi.org/10.1016/j.cej.2019.03.173
Khalil, A., Habib-ur-Rehman, Sh., Muhammad, A., Syed, Sh., Ejaz, H., Hafiza, A., Sajidah, P., & Asif, A. (2021). Effect of metal atom in zeolitic imidazolate frameworks (ZIF-8 & 67) for removal of Pb2+ & Hg2+ from water. Food and Chemical Toxicology, 149, 112008. https://doi.org/10.1016/j.fct.2021.112008
Ajmal, M., Rao, R. A. K., & Khan, M. (2005). Adsorption of copper from aqueous solution on Brassica cumpestris (mustard oil cake). J. Hazard. Mater, 122, 177-183. https://doi.org/10.1016/j.jhazmat.2005.03.029
Larous, S., Meniai, A. H. & Lehocine, M. B. (2005). Experimental study of the removal of copper from aqueous solutions by adsorption using sawdust. Desalination, 185, 483-490. https://doi.org/10.1016/j.desal.2005.03.090
Jia, S., Yang, Z., Yang, W., Zhang, T., Zhang, S., Yang, X., & Dong, Y. (2016). Removal of Cu(II) and tetracycline using an aromatic rings-functionalized chitosan-based flocculant: enhanced interaction between the flocculant and the antibiotic. Chem. Eng. J, 283, 495-503. https://doi.org/10.1016/j.cej.2015.08.003
Ye, S. J., Zeng, G. M., Hu Zhang, H. P., Liang, C., Dai, J., Liu, Z. F., Xiong, W. P., Wan, J., Xu, P., & Cheng, M. (2017). Co-occurrence and interactions of pollutants, and their impacts on soil remediation - a review. Crit. Rev. Environ. Sci. Technol, 47, 1528-1553. https://doi.org/10.1080/10643389.2017.1386951
Weng, X. L., Lin, S., Zhong, Y. H., & Chen, Z. L. (2013). Chitosan stabilized bimetallic Fe/Ni nanoparticles used to remove mixed contaminants-amoxicillin and Cd(II) from aqueous solutions. Chem. Eng. J, 229, 27-34. https://doi.org/10.1016/j.cej.2013.05.096
Chen, Q., Luo, Z., Hills, C., Xue, G., & Tyrer, M. (2009) Precipitation of heavy metals from wastewater using simulated flue gas: sequent additions of fly ash, lime and carbon dioxide. Water Research, 43, 10, 2605-2614. https://doi.org/10.1016/j.watres.2009.03.007
Gharabaghi, M., Irannajad, M., & Azadmehr, A. R. (2012). Selective sulphide precipitation of heavy metals from acidic polymetallic aqueous solution by thioacetamide. Ind. Eng. Chem. Res, 51, 954-963. https://doi.org/10.1021/ie201832x
Vilensky, M. Y., Berkowitz, B., & Warshawsky, A. (2002). In situ remediation of groundwater contaminated by heavy- and transition-metal ions by selective ion-exchange methods. Environ. Sci. Technol, 36, 1851-1855. https://doi.org/10.1021/es010313
Ritchie, S. M. C., Kissick, K. E., Bachas, L. G., Sikdar, S. K., Parikh, C., & Bhattacharyya, D. (2001). Polycysteine and other polyamino acid functionalized microfiltration membranes for heavy metal capture. Environ. Sci. Technol, 35, 3252-3258. https://doi.org/10.1021/es010617w
Celis, R., Hermosin, M. C., & Cornejo, J. (2000). Heavy metal adsorption by functionalized clays. Environ. Sci. Technol, 34, 4593-4599. https://doi.org/10.1021/es000013c
Wingenfelder, U., Hansen, C., Furrer, G., & Schulin, R. (2005). Removal of heavy metals from mine waters by natural zeolites. Environ. Sci. Technol, 39, 4606-4613. https://doi.org/10.1021/es048482s
Yuvaraja, G., Subbaiah, M. V., & Krishnaiah, A. (2012). Caesalpinia bonducella leaf powder as biosorbent for Cu(II) removal from aqueous environment: kinetics and isotherms. Ind. Eng. Chem. Res, 51, 11218-11225. https://doi.org/10.1021/ie203039m
Yujie, Zh., Zhiqiang, X., Zhuqing, W., Xuhui, F., Ying, W., & Aiguo, W. (2016). Unveiling the adsorption mechanism of zeolitic imidazolate framework-8 with high efficiency for removal of copper ions from aqueous solutions. Dalton Trans. The Royal Society of Chemistry, 45, 12653-12660. https://doi,org/10.1039/C6DT01827K
Ke Li., Nicholas, M., Lei, Ch., Huang, J., Paulette, S., Desmond, A., David, E., Wencong, X., Guang, Li., & Hai L. (2021). Sustainable application of ZIF-8 for heavy-metal removal in aqueous solutions. Sustainability, 13, 984. https://doi.org/10.3390/su13020984
Wan, N., & Hanafiah, W. (2008). Removal of heavy metal ions from wastewater by chemically modified plant wastes as adsorbents: a review. Bioresource Technology, 99, 3935-3948. https://doi.org/10.1016/j.biortech.2007.06.011
Yutian, Zh., Xudong, Zh., Hongliang, H., & Li, Zh. (2015). Selective removal of transition metal ions from aqueous solution by metal-organic frameworks. Royal Society of Chemistry, 5(88), 72107-72112. https://doi.org/10.1039/c5ra09897a
Gavrilescu, M. (2004). Removal of heavy metals from the environment by biosorption. Eng. Life Sci, 4, 219-232. https://doi.org/10.1002/elsc.200420026
Fu, F., & Wang, Q. (2011). Removal of heavy metal ions from wastewaters: a review. Journal of Environmental Management, 92 (3), 407-418. https://doi.org/10.1016/j. jenvman.2010.11.011
Kim, H. S., Kim, Y. J., & Seo, Y. R. (2015). An overview of carcinogenic heavy metal: molecular toxicity mechanism and prevention. J. Cancer Prev, 20, 232-240. https://doi.org/10.15430/JCP.2015.20.4.232
Mahfuza, F., Md. Marjanul, H., Shamsunnahar, S., Anindita, S., Md. Razzak., & Ruhul, A. (2022). Types and treatment technology of industrial wastewater. Journal of Chemical, Environmental and Biological Engineering, 6, 56-69. https://doi.org/ 10.11648/j.jcebe.20220602.12
Muhammad, S., Lila, B., Mohd, D., Nur, S., Muhammad, R., Nik, A., Zulfan, A., & Fuad, N. (2020). Integrated membrane–electrocoagulation system for removal of celestine blue dyes in wastewater. Membranes, 10(8), 184. https://doi.org/10.3390/membranes10080184
Asano, T. (2002). The 2001 Stockholm water prize laureate lecture, water science and technology, 45, 23-33. Edition: LD/BI-499-06. Publisher: Technological Centre Gaiker, Zamudio, Spain
Wirzal, M. D. H., Mohd, Y. A. R., Zima, J., & Barek, J. (2015). Voltammetric determination of nifedipine at a hanging mercury drop electrode and a mercury meniscus modified silver amalgam electrode. Int. J. Electrochem. Sci, 10, 4571-4584. https://doi.org/10.1007/s11696-020-01243-w
Abo-Farha, S. A., Abdel-Aal, A. Y., Ashour, I. A., & Garamon, S. E. (2009). Removal of some heavy metal cations by synthetic resin purolite C100. Journal of Hazardous Materials, 169 (1–3), 190-194. https://doi.org /10.1016/j.jhazmat.2009.03.086
Bakhtiari, N., & Azizian, S. (2015) Adsorption of copper ion from aqueous solution by nanoporous MOF-5: a kinetic and equilibrium study. Journal of Molecular Liquids, 206, 114-118. https://doi.org/10.1016/j.molliq.2015. 02.009
Babel, S., & Kurniawan, T. A. (2004). Cr(VI) removal from synthetic wastewater using coconut shell charcoal and commercial activated carbon modified with oxidizing agents and/or chitosan. Chemosphere, 54, 951–967. https://doi.org/10.1016/j.chemosphere.2003.10.001
Wan N. W. S., & Hanafiah, M. A. K. M. (2008). Removal of heavy metal ions from wastewater by chemically modified plant wastes as adsorbents: a review. Bioresource Technology, 99, 3935-3948. https://doi.org/10.1016/j. biortech.2007.06.011
Al-Saydeh, S. A., El-Naas, M. H., & Zaidi, S. J. (2017). Copper removal from industrial wastewater: A comprehensive review. Journal of Industrial and Engineering Chemistry, 56, 35-44. https://doi.org/10.1016/j.jiec.2017.07.026
Gnanaselvan, G., Sasikumar, B., Gangasalam, A., & Diganta, B. (2019). Removal of hazardous material from wastewater by using metal organic framework (MOF) embedded polymeric membranes. Separation science and technology, 54, 3, 434-446. https://doi.org/10.1080/01496395.2018.1508232
Simin, F., Xiaoli, Zh., Dunyun, Sh., & Zheng, W. (2021). Zeolitic imidazolate framework-8 (ZIF-8) for drug delivery: a critical review. Chem. Sci. Eng, 15(2), 221-237. https://doi.org/10.1007/s11705-020-1927-8
Park, K. S., Ni, Z., Cote, A. P., Yong, J., Huang, R., Uribe-Romo, F. J., Chae, H. K., O'Keeffe, M., & Yaghi, O. M. (2006). Exceptional chemical and thermal stability of zeolitic imidazolate frameworks. PNAS, 103(27), 10186-10191. https://doi.org/10.1073/pnas.0602439103
Lu, G., & Hupp, J. T. (2010). Metal-organic frameworks as sensors: a ZIF-8 based fabry-perot device as a selective sensor for chemical vapors and gases. J. Am. Chem. Soc, 132(23), 7832-3. https://doi.org/10.1021/ja101415b
Vasconcelos, I. B., Da Silva, T. G., Militao, G. C. G., Soares, T. A., Rodrigues, N. M., Rodrigues, M. O., Da Costa, N. B., Freire, R. O., & Junior, S. A. (2012). Cytotoxicity and slow release of the anti-cancer drugdoxorubicin from ZIF-8. RSC Adv, 2, 9437-9442. https://doi.org/10.1039/C2RA21087H
Peralta, D., Chaplais, G., Simon-Masseron, A., Barthelet, K., Chizallet, C., Quoineaud, A. A., & Pirngruber, G. D. (2012). Comparison of the behavior of metal–organic frameworks and zeolites for hydrocarbon separations. J. Am. Chem. Soc, 134, 8115-8126. https://pubs.acs.org/doi/abs/10.1021/ja211864w
Chizallet, C., Lazare, S., Bazer-Bachi, D., & Bonnier, F. (2010). Catalysis of transesterification by a nonfunctionalized metal-organic framework: acido-basicity at the external surface of ZIF-8 probed by FTIR and ab initio calculations. J. Am. Chem. Soc, 132 (35), 12365-12377. https://pubs.acs.org/doi/abs/10.1021/ja103365s
Nguyen, L. T. L., Le, K. K. A., Phan, N. T. S., & Chin, A. (2012). Zeolite imidazolate framework ZIF-8 catalyst for friedel-crafts acylation. J. Catal, 33, 688-696. https://doi.org/10.1016/S1872-2067(11)60368-9
Tran, U. P. N., Le, K. K. A., & Phan, N. T. S. (2011). Expanding applications of metal-organic frameworks: zeolite imidazolate framework ZIF-8 as an efficient heterogeneous catalyst for the knoevenagel reaction. ACS Catal, 1, 120-127. https://doi.org/10.1021/cs1000625
Zhao, X.-J., Fang, X.-L., Wu, B.-H., Zheng, L.-S., & Zheng, N.-F. (2014). Facile synthesis of size-tunable ZIF-8 nanocrystals using reverse micelles as nanoreactors. Sci. China Chem, 57, 141-146. https://doi.org/10.1007/s11426-013-5008-4
Farrusseng, D. (2011). Metal-organic frameworks: applications from catalysis to gas storage, Wiley-VCH. https://doi.org 10.1002/9783527635856
Venna, S. R., Jasinski, J. B., & Carreon, M. A. (2010). Structural evolution of zeolitic imidazolate framework-8. J. Am. Chem. Soc, 132, 18030-18033. https://doi.org/10.1021/ja109268m
Cravillon, J., Nayuk, R., Springer, S., Feldhoff, A., Huber, K., & Wiebcke, M. (2011). Controlling zeolitic imidazolate framework nano- and microcrystal formation: insight into crystal growth by time-resolved in situ static light scattering. Chem. Mater, 23, 2130-2141. https://doi.org/10.1021/cm103571y
Meipeng, J., Bao, L., Ruiping, L., Jiuhui, Q., Huanting, W., & Xiwang, Zh. (2015). Water-based synthesis of zeolitic imidazolate framework-8 with high morphology level at room temperature. RSC Advances, 5(60). https://doi.org/10.1039/C5RA04033G
Yao, J., He, M., Wang, K., Chen, R., Zhong, Z., & Wang, H. (2013). High-yield synthesis of zeolitic imidazolate frameworks from stoichiometric metal and ligand precursor aqueous solutions at room temperature. Cryst Eng Comm, 15, 3601-3606. https://doi.org/10.1039/C3CE27093A
Cho, H.-Y., Kim, J., Kim, S.-N., & Ahn, W.-S. (2013). High yield 1-L scale synthesis of ZIF-8 via a sonochemical route. Microporous Mesoporous Mater, 169, 180-184. https://doi.org/10.1016/j.micromeso.2012.11.012
Gross, A., Sherman, E., & Vajo, J. (2012). Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks. Dalton Trans, 41, 5458-5460. https://doi.org/10.1039/c2dt30174a
Pan, Y., Liu, Y., Zeng, G., Zhao, L., & Lai, Z. (2011). Rapid synthesis of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals in an aqueous system. Chem. Commun., 47, 2071-2073. https://doi.org/10.1039/c0cc05002d
Marquez, A. G., Horcajada, P., Grosso, D., Ferey, G., Serre, C., Sanchez, C., & Boissiere, C. (2013). Green scalable aerosol synthesis of porous metal–organic frameworks. Chem. Commun, 49, 3848-3850. https://doi.org/10.1039/c3cc39191d
Wu, C. S., Xiong, Z. H., Li, C., & Zhang, J. M. (2015). Zeolitic imidazolate metal organic framework ZIF-8 with ultra-high adsorption capacity bound tetracycline in aqueous solution. RSC Adv, 5, 82127–82137. https://doi.org/10.1039/c5ra15497a
Omar, K., & Joseph, T. (2010). Rational design, synthesis, purification, and activation of metal-organic framework materials. Accounts of Chemical Research, 43(8), 1166-1175. https://doi.org/10.1021/ar1000617
Yu-Ri, L., Min-Seok, J., Hye-Young, Ch., Hee Jin, K, Sangho, K., & Wha-Seung, A. (2015). ZIF-8: a comparison of synthesis methods. Chemical Engineering Journal, 271. https://doi.org/10.1016/j.cej.2015.02.094
Christian, D., Raffaele, R., Kang, L., Darren, B., & Paolo, F. (2017). Metal–organic frameworks at the biointerface: synthetic strategies and applications. American Chemical Society, 50(6), 1423-1432. https://pubs.acs.org/doi/abs/10.1021/acs.accounts.7b00090
Nilay, K., Berna, T., Levent, Y., & Halil, K. (2014). Synthesis of ZIF-8 from recycled mother liquors. Microporous Mesoporous Mater, 198, 291-300. https://doi.org/10.1016/j.micromeso.2014.07.052
Li, Y. S., Liang, F. Y., Bux, H., Feldhoff, A., Yang, W. S., & Caro, J. (2010). Molecular sieve membrane: supported metal-organic framework with high hydrogen selectivity. Angew. Chem. - Int. Ed, 49, 548-551. https://doi.org/10.1002/ange.200905645
Zhou, H. C., Long, J. R., & Yaghi, O. M. (2012). Introduction to metal-organic frameworks. Chem. Rev, 112, 673. https://doi.org/10.1021/cr300014x
Park, K. S., Ni, Z., Côté, A. P., Choi, J. Y., Huang, R., Uribe-Romo, F. J., Chae, H. K., O'Keeffe, M., & Yaghi, O. M. (2006). Exceptional chemical and thermal stability of zeolitic imidazolate frameworks. Proc. Natl. Acad. Sci. U.S.A., 103, 10186-10191. https://doi.org/10.1073/pnas.0602439103
Kida, K., Okita, M., Fujita, K., Tanaka, S., & Miyake, Y. (2013). Formation of high crystalline ZIF-8 in an aqueous solution. Cryst Eng Comm, 15, 1794. https://doi.org/10.1039/C2CE26847G
Lin, W., Rieter, W. J., & Taylor, K. M. L. (2009). Modular synthesis of functional nanoscale coordination polymers. Angew Chem, Int Ed, 48, 650-658. https://doi.org/10.1002/ange.200803387
Aya, T., Mohamed, A., Ezzat, A., Abdalla, El., & Fatma, M. (2025). Effective removal of heavy metal ions (Pb, Cu, and Cd) from contaminated water by limestone mine wastes. Sci Rep, 15, 1680. https://doi.org/10.1038/s41598-024-82861-2
Junfeng, Q., Fuan, S., & Lizhen, Q. (2012). Hydrothermal synthesis of zeolitic imidazolate framework-67 (ZIF-67) nanocrystals. Mater Lett, 82, 220-223. https://doi.org/10.1016/j.matlet.2012.05.077
Yao, J., He, M., & Wang, H. (2015). Strategies for controlling crystal structure and reducing usage of organic ligand and solvents in the synthesis of zeolitic imidazolate frameworks. Cryst Eng Comm, 17, 4970-4976. https://doi.org/10.1039/C5CE00663E
Lee, Yu-Ri., Min-Seok, J., Hye-Young, Ch., Hee-Jin, K., Sangho, Kim., & Wha-Seung, A. (2015) ZIF-8: a comparison of synthesis methods. Chemical Engineering Journal, 271, 276-280. https://doi.org/10.1016/j.cej.2015.02.094
Kida, K., Okita, M., Fujita, K., Tanaka, S., & Miyake, Y. (2013). Formation of high crystalline ZIF-8 in an aqueous solution. Cryst Eng Comm, 15(9), 1794. https://doi.org/10.1039/C2CE26847G
Huang, X. C., Lin, Y. Y., Zhang, J. P., & Chen, X. M. (2006). Ligand-directed strategy for zeolite-type metal-organic frameworks: zinc(II) imidazolates with unusual zeolitic topologies. Angewandte Chemie International Edition, 45(10), 1557-1559. https://doi.org/10.1002/anie.200503778
Zhang, J. P., Zhu, A. X., Lin, R. B., Qi, X. L, & Chen, X. M. (2011). Pore surface tailored sod-type metal-organic zeolites. Advanced Materials, 23(10), 1268-1271. https://doi.org/10.1002/adma.201004028
Zhu, A. X, Lin, R. B., Qi, X. L, Liu, Y., Lin, Y.Y., Zhang, J. P., & Chen, X. M. (2012). Zeolitic metal azolate frameworks (MAFs) from ZnO/Zn(OH)2 and monoalkyl-substituted imidazoles and 1,2,4-triazoles: efficient syntheses and properties. Microporous and Mesoporous Materials, 157, 42–49. https://doi.org /10.1016/j.micromeso.2011.11.033
Cravillon, J., Münzer, S., Lohmeier, S.J., Feldhoff, A., Huber, K., & Wiebcke, M. (2014). Rapid room-temperature synthesis and characterization of nanocrystals of a prototypical zeolitic imidazolate framework. Chem. Commun, 50, 13260. https://doi.org /10.1039/C4CC06491G
Cravillon, J., Nayuk, R., Springer, S., Feldhoff, A., Huber, K., & Wiebcke, M. (2011). Controlling zeolitic imidazolate framework nano- and microcrystal formation: Insight into crystal growth by time-resolved in situ static light scattering. Chemistry of Materials, 23(8), 2130-2141. https://doi.org/10.1021/cm103571y
Cravillon, J., Schröder, C. A., Bux, H., Rothkirch, A., Caro, J., & Wiebcke, M. (2012). Formate modulated solvothermal synthesis of ZIF-8 investigated using time-resolved in situ X-ray diffraction and scanning electron microscopy. Cryst Eng Comm, 14(2), 492-498. https://doi.org/10.1039/C1CE06002C
Bennett, T. D., Saines, P. J., Keen, D. A., Tan, J. C., & Cheetham, A. (2013). Ballmilling- induced amorphization of zeolitic imidazolate frameworks (ZIFs) for the irreversible trapping of iodine. Chemistry (Weinheim an der Bergstrasse, Germany), 19(22), 7049-7055. https://doi.org/10.1002/chem.201300216
Nune, S. K., Thallapally, P. K., Dohnalkova, A., Wang, C., Liu, J., & Exarhos, G. J. (2010). Synthesis and properties of nano zeolitic imidazolate frameworks. Chemical Communications, 46(27), 4878-4880. https://doi.org/10.1039/c002088e
He, M., Yao, J., Li, L., Wang, K., Chen, F., & Wang, H. (2013). Synthesis of zeolitic imidazolate framework-7 in a water/ethanol mixture and its ethanol-induced reversible phase transition. ChemPlusChem, 78(10), 1222-1225. https://doi.org/10.1002/cplu.201300193
Shen, K., Zhang, L., Chen, X., Liu, L., Zhang, D., Han, Y., Chen, J., Long, J., Luque, R., Li, Y., & Chen, B. (2018). Ordered macro-microporous metalorganic framework single crystals. Science, 359(6372), 206-210. https://doi.org/10.1126/science.aao3403
Hu, L., Yan, Z., Zhang, J., Peng, X., Mo, X., Wang, A., & Chen, L. (2019). Surfactant aggregates within deep eutectic solvent-assisted synthesis of hierarchical ZIF-8 with tunable porosity and enhanced catalytic activity. Journal of Materials Science, 54(16), 11009-11023. https://doi.org/10.1007/s10853-019-03644-z
Chen, Y., & Tang, S. (2019). Solvothermal synthesis of porous hydrangea-like zeolitic imidazole framework-8 (ZIF-8) crystals. Journal of Solid State Chemistry, 85, 68-74. https://doi.org/10.1016/j.jssc.2019.04.034
Troyano, J., Carne-Sanchez, A., Avci, C., Imaz, I., & Maspoch, D. (2019). Colloidal metal-organic framework particles: The pioneering case of ZIF-8. Chemical Society Reviews, 48(23), 5534–5546. https://doi.org/10.1039/C9CS00472F
Pan, Y., Liu, Y., Zeng, G., Zhao, L., & Lai, Z. Rapid synthesis of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals in an aqueous system. (2011). Chemical Communications, 47(7), 2071-2073. https://doi.org/10.1039/c0cc05002d
Tanaka, S., Kida, K., Okita, M., Ito, Y., & Miyake, Y. (2012). Size-controlled synthesis of zeolitic imidazolate framework-8 (ZIF-8) crystals in an aqueous system at room temperature. Chemistry Letters, 41(10), 1337-1339. https://doi.org/10.1246/cl.2012.1337
Yao, J., He, M., Wang, K., Chen, R., Zhong, Z., & Wang, H. (2013). High-yield synthesis of zeolitic imidazolate frameworks from stoichiometric metal and ligand precursor aqueous solutions at room temperature. Cryst Eng Comm, 15(18), 3601. https://doi.org/10.1039/C3CE27093A
He, M., Yao, J., Liu, Q., Wang, K., Chen, F., & Wang, H. (2014). Facile synthesis of zeolitic imidazolate framework-8 from a concentrated aqueous solution. Microporous and Mesoporous Materials, 184, 55–60. https://doi.org/10.1016/j.micromeso.2013.10.003
Seoane, B., Zamaro, J. M., Tellez, C., & Coronas, J. (2012). Sonocrystallization of zeolitic imidazolate frameworks (ZIF-7, ZIF-8, ZIF-11 and ZIF-20). Cryst Eng Comm, 14(9), 3103. https://doi.org/10.1039/C2CE06382D
Cho, H. Y., Kim, J., Kim, S. N., & Ahn, W. S. (2013). High yield 1-L scale synthesis of ZIF-8 via a sonochemical route. Microporous and Mesoporous Materials, 169, 180-184. https://doi.org/10.1016/j.micromeso.2012.11.012
Suslick, K. S., Hammerton, D. A., & Cline, R. E. (1986). Sonochemical hot spot. Journal of the American Chemical Society, 108(18), 5641-5642. https://pubs.acs.org/doi/10.1021/ja00278a055
Son, W. J., Kim, J., Kim, J., & Ahn, W. S. (2008). Sonochemical synthesis of MOF-5. Chemical Communications, (47), 6336–6338. https://doi.org/10.1039/b814740j
Schlesinger, M., Schulze, S., Hietschold, M., & Mehring, M. (2010). Evaluation of synthetic methods for microporous metal-organic frameworks exemplified by the competitive formation of [Cu2(btc)3(H2O)3]. Microporous and Mesoporous Materials, 132(1-2), 121-127. https://doi.org/10.1016/j.micromeso.2010.02.008
Fernández-Bertrán, J. F., Hernández, M. P., Reguera, E., Yee-Madeira, H., Rodriguez, J., Paneque, A., & Llopiz, J. C. (2006). Characterization of mechanochemically synthesized imidazolates of Ag+1, Zn+2, Cd+2, and Hg+2: solid state reactivity of cations. Journal of Physics and Chemistry of Solids, 67(8), 1612-1617. https://doi.org/10.1016/j.jpcs.2006.02.006
Adams, C. J., Colquhoun, H. M., Crawford, P. C., Lusi, M., & Orpen, A. G. (2007). Solid-state interconversions of coordination networks and hydrogen- bonded salts. Angewandte Chemie International Edition, 119(7), 1142–1146. https://doi.org/10.1002/anie.200603593
Beldon, P. J., Fabian, L., Stein, R. S., Thirumurugan, A., Cheetham, A. K., & Friscic, T. (2010). Rapid room-temperature synthesis of zeolitic imidazo-late frameworks by using mechanochemistry. Angewandte Chemie International Edition, 49(50), 9640-9643. https://doi.org/10.1002/anie.201005547
Braga, D., Curzi, M., Johansson, A., Polito, M., Rubini, K., & Grepioni, F. (2006). Simple and quantitative mechanochemical preparation of a porous crystalline material based on a 1D coordination network for uptake of small molecules. Angewandte Chemie International Edition, 45(1), 142-146. https://doi.org/10.1002/anie.200502597
Friscic, T., Reid, D. G., Halasz, I., Stein, R. S., Dinnebier, R. E., & Duer, M. J. (2010). Ion- and liquid-assisted grinding: Improved mechanochemical synthesis of metal-organic frameworks reveals salt inclusion and anion templating. Angewandte Chemie International Edition, 49(4), 712-715. https://doi.org/10.1002/anie.200906583
Tanaka, S., Kida, K., Nagaoka, T., Ota, T., & Miyake, Y. (2013). Mechanochemical dry conversion of zinc oxide to zeolitic imidazolate framework. Chemical Communications, 49(72), 7884-7886. https://doi.org/10.1039/c3cc43028f
Qiaoling, Zh., Tian, Yu., Rongkang, Y., Xin, G., & Yao, Ch. (2025). ZIF‑8 and its derivative adsorbents for heavy metal removal in water: a review. ACS Omega, 10, 47790-47801. https://doi.org/10.1021/acsomega.5c05692
Ahmad, K., Shah, H.-U.-R., Ashfaq, M., Shah, S. S. A., Hussain, E., Naseem, H. A., Parveen, S., & Ayub, A. (2021). Effect of metal atom in zeolitic imidazolate frameworks (ZIF-8 & 67) for removal of Pb2+ & Hg2+ from water. Food Chem. Toxicol, 149, 112008. https://doi.org/10.1016/j.fct.2021.112008
Li, R., Li, W., Jin, C., He, Q., & Wang, Y. (2020). Fabrication of ZIF-8@TiO2 micron composite via hydrothermal method with enhanced absorption and photocatalytic activities in tetracycline degradation. J. Alloys Compd, 825, 154008. https://doi.org/ 10.1016/j.jallcom.2020.154008
Nalesso, S., Varlet, G., Bussemaker, M. J., Sear, R. P., Hodnett, M., Monteagudo-Olivan, R., Sebastian, V., Coronas, J., & Lee, J. (2021). Sonocrystallisation of ZIF-8 in water with high excess of ligand: effects of frequency, power and sonication time. Ultrason. Sonochem, 76, 105616. https://doi.org/10.1016/j.ultsonch.2021.105616
Głowniak, S., Szczęśniak, B., Choma, J., & Jaroniec, M. (2021). Mechanochemistry: toward green synthesis of metal-organic frameworks. Mater. Today, 46, 109-124. https://doi.org/ 10.1016/j.mattod.2021.01.008
Hong, Y., Liao, W., Yan, Z., Bai, Y., Feng, C., Xu, Z., Xu, D., & Lim, K. (2020). Progress in the research of the toxicity effect mechanisms of heavy metals on freshwater organisms and their water quality criteria in China, J. Chem.-NY. https://doi.org/10.1155/2020/9010348
Baby, J., Raj, J. S., Biby, E. T., Sankarganesh, J., Jeevitha, M. V, Ajisha, S. U. & Rajan, S. S. (2010). Toxic effect of heavy metals on aquatic environment. Int. J. Biol. Chem. Sci, 4(4), 939-952. https://doi.org/10.4314/ijbcs.v4i4.62976
Gaetke, L. M., & Chow, C. K. (2003). Copper toxicity, oxidative stress, and antioxidant nutrients. Toxicology, 189, 147-163. https://doi.org/10.1016/S0300-483X(03)00159-8
Briffa, J., Sinagra, E., & Blundell, R. (2020). Heavy metal pollution in the environment and their toxicological effects on humans. Heliyon, 6, 4691. https://doi.org/10.1016/j.heliyon.2020.e04691
Zeitoun, M. M., & Mehana, E. E. (2014). Impact of water pollution with heavy metals on fish health: overview and updates. Global Veterinaria, 12, 219-231. https://doi.org/10.5829/idosi.gv.2014.12.02.82219
Li, Z., Wang, L., Qin, L., Lai, C., Wang, Z., Zhou, M., Xiao, L., Liu, S., & Zhang, M. (2021). Recent advances in the application of water-stable metal-organic frameworks: adsorption and photocatalytic reduction of heavy metal in water. Chemosphere, 285, 131432. https://doi.org/10.1016/j.chemosphere.2021.131432
Fu, F., & Wang, Q. (2011). Removal of heavy metal ions from wastewaters: a review. J. Environ. Manage, 92, 407-418. https://doi.org/10.1016/j.jenvman.2010.11.011
Arbabi, M. N., & Golshani, N. (2016). Removal of copper ions Cu(II) from industrial wastewater: a review of removal methods. Int. J. Epidemiol. Res, 3, 283-293. https://doi.org/10.1016/j.jiec.2017.07.026
Azimi, A., Azari, A., Rezakazemi, M., & Ansarpour, M. (2017). Removal of heavy metals from industrial wastewaters: a review. Chem Bio Eng Rev, 37-59. https://doi.org/10.1002/cben.201600010
Qasem, N. A., Mohammed, R. H., & Lawal, D. U. (2021). Removal of heavy metal ions from wastewater: a comprehensive and critical review. Clean Water, 4, 1-15. https://doi.org/10.1038/s41545-021-00127-0
Ahmed H. Algureiri Yossor Abdulmajeed (2016). Removal of heavy metals from industrial wastewater by using ro membrane. Iraqi Journal of Chemical and Petroleum Engineering, 17(4), 125-136. https://doi.org/10.31699/IJCPE.2016.4.12
Lei, C., Gao, J., Ren, W., Xie, Y., Abdalkarim, S. Y. H., Wang, S., Ni, Q., & Yao, J. (2019). Fabrication of metal-organic frameworks@ cellulose aerogels composite materials for removal of heavy metal ions in water. Carbohyd. Polym, 205, 35-41. https://doi.org/10.1016/j.carbpol.2018.10.029
Aklil, A., Mouflih, M., & Sebti, S. (2004). Removal of heavy metal ions from water by using calcined phosphate as a new adsorbent. J. Hazard. Mater, 112, 183-190. https://doi.org/10.1016/j.jhazmat.2004.05.018
Orolínova´a, Z., Mockovˇciakov´a, A., & ˇSkvarla, J. (2010). Sorption of cadmium(II) from aqueous solution by magnetic clay composite. Desalin Water Treat, 24, 284-292. https://doi.org/10.13189/eee.2013.010206
Naat, J. N., Neolaka, Y. A., Lapailaka, T., Tj, R. T., Sabarudin, A., Darmokoesoemo, H., & Kusuma, H. S. (2021). Adsorption of Cu(II) and Pb(II) using silica@ mercapto (hs@m) hybrid adsorbent synthesized from silica of Takari sand: optimization of parameters and kinetics. Rasayan J. Chem, 14, 550-560. https://doi.org/10.31788/RJC.2021.1415803
Mo, Z., Tai, D., Zhang, H., & Shahab, A. (2022). A comprehensive review on the adsorption of heavy metals by zeolite imidazole framework (ZIF-8) based nanocomposite in water. Chem. Eng. J, 136320. https://doi.org/10.1016/j.cej.2022.136320
Qu, H., Huang, L., Han, Z., Wang, Y., Zhang, Z., Wang, Y., Chang, Q., Wei, N., Kipper, M. J., & Tang, J. (2021). A review of graphene-oxide/metal–organic framework composites materials: characteristics, preparation and applications. J. Porous Mat, 28, 1837-1865. https://doi.org/10.1007/s10934-021-01125-w
Wang, Q., Sun, Y., Li, S., Zhang, P., & Yao, Q. (2020). Synthesis and modification of ZIF-8 and its application in drug delivery and tumor therapy. RSC Adv, 10, 37600-37620. https://doi.org/10.1039/D0RA07950B
Yang, H., Wang, N., Wang, L., Liu, H., An, Q., & Ji, S. (2018). Vacuum-assisted assembly of ZIF- 8@ GO composite membranes on ceramic tube with enhanced organic solvent nanofiltration performance. J. Membrane Sci., 545, 158-166. https://doi.org/10.1016/j.memsci.2017.09.074
Li, D., & Xu, F. (2021). Removal of Cu (II) from aqueous solutions using ZIF-8@ GO composites. J. Solid State Chem., 302, 122406. https://doi.org/ 10.1016/j.jssc.2021.122406
Chen, B., Wan, C., Kang, X., Chen, M., Zhang, C., Bai, Y., & Dong, L. (2019). Enhanced CO2 separation of mixed matrix membranes with ZIF-8@ GO composites as fillers: effect of reaction time of ZIF-8@ GO. Sep. Purif. Technol., 223, 113-122. https://doi.org/10.1016/j.seppur.2019.04.063
Загрузки
Опубликован
Выпуск
Раздел
Лицензия
Copyright (c) 2026 N. Dalabayeva, G. Kostakis, N. Sarova, G. Sdikova, Zh. Korganbayeva, T. Akylbekova (Author)
Это произведение доступно по лицензии Creative Commons «Attribution-NonCommercial» («Атрибуция — Некоммерческое использование») 4.0 Всемирная.
