Synthesis and some transformations of carboranyl-containing nitroalkanes

Abstract

The article presents the reactions of the addition of C-metal derivatives of carboranes with β -
nitrostyrene: p-dimethylamino-β-nitrostyrene, β - nitrostyrene, 2,5 - dimethoxy-β-nitrostyrene, 3,4,5 - trimethoxy-β-nitrostyrene . The reactions of the interaction of these compounds with C-metal derivatives of carboranes
were studied. The following compounds were synthesized: isopropyl-o-carborane – β – nitrostyrene, isopropylo-carborane –3,4,5-trimethoxy – β – nitrostyrene, isopropyl-o-carborane-2,5-dimethoxy-β-nitrostyrene,
isopropyl-o -carboran-p-dimethylamino-β-nitrostyrene. The resulting compounds were characterized by NMR
and IR spectroscopy